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authorKarl Berry <karl@freefriends.org>2017-09-10 20:56:37 +0000
committerKarl Berry <karl@freefriends.org>2017-09-10 20:56:37 +0000
commit17ae18d7db87b958fb98d507710e615be1d4cc17 (patch)
tree10b999a6128193a7050af3fcc6cb961e298ead62 /Master/texmf-dist/doc/latex/beilstein
parentfe7eb475424b6da9570efd4cb2ab66f07480c614 (diff)
beilstein (10sep17)
git-svn-id: svn://tug.org/texlive/trunk@45265 c570f23f-e606-0410-a88d-b1316a301751
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-rw-r--r--Master/texmf-dist/doc/latex/beilstein/CHANGELOG.md30
-rw-r--r--Master/texmf-dist/doc/latex/beilstein/README.md26
-rw-r--r--Master/texmf-dist/doc/latex/beilstein/beilstein-template.bib319
-rw-r--r--Master/texmf-dist/doc/latex/beilstein/beilstein-template.tex238
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diff --git a/Master/texmf-dist/doc/latex/beilstein/BJNANO_Technical_Handbook.pdf b/Master/texmf-dist/doc/latex/beilstein/BJNANO_Technical_Handbook.pdf
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diff --git a/Master/texmf-dist/doc/latex/beilstein/CHANGELOG.md b/Master/texmf-dist/doc/latex/beilstein/CHANGELOG.md
new file mode 100644
index 00000000000..65f7a44b89a
--- /dev/null
+++ b/Master/texmf-dist/doc/latex/beilstein/CHANGELOG.md
@@ -0,0 +1,30 @@
+# Change Log
+All notable changes to this project will be documented in this file.
+
+The format is based on [Keep a Changelog](http://keepachangelog.com/)
+and this project adheres to [Semantic Versioning](http://semver.org/).
+
+
+## 1.2 - 2017-08-21
+
+### Added
+- Structure modified and files added for CTAN publication
+
+### Changed
+- Updated documentation
+
+### Fixed
+- Option handling now compatible to recent `babel` versions
+- `note` is only output once for `@misc` bib entries
+- Fix for the declaration of `\-` as a robust command. There is a conflict between package `bpchem` and the latest `LaTeX` release
+
+
+## 1.1 - 2010-08-16
+
+### Fixed
+- Page number bug fix
+
+
+## 1.0 - 2010-05-11
+First official release at BJNANO public website
+
diff --git a/Master/texmf-dist/doc/latex/beilstein/README.md b/Master/texmf-dist/doc/latex/beilstein/README.md
new file mode 100644
index 00000000000..07611f135ef
--- /dev/null
+++ b/Master/texmf-dist/doc/latex/beilstein/README.md
@@ -0,0 +1,26 @@
+# beilstein
+
+ beilstein -- Support for submissions to the ``Beilstein Journal
+ of Nanotechnology'' published by the Beilstein-Institut
+ for the Advancement of Chemical Sciences
+ Version: 1.2
+ E-mail: journals-support@beilstein-institut.de
+ License: Released under the LaTeX Project Public License v1.3c or later
+ See http://www.latex-project.org/lppl.txt
+
+The Beilstein bundle provides a LaTeX class file and a BibTeX
+style file in accordance with the requirements of submissions to
+the [Beilstein Journal of Nanotechnology]. Although the
+files can be used for any kind of document, they have only been
+designed and tested to be suitable for submission to the [Beilstein Journal of Nanotechnology].
+
+
+Stable versions are uploaded to CTAN (https://www.ctan.org/pkg/beilstein).
+In addition you will find the most recent version at https://www.beilstein-journals.org/bjnano/templates.
+The most recent documentation is available at BJNANO_Technical_Handbook.pdf within the doc directory.
+`texdoc beilstein` should give you this file. It includes a short description how to use the template and
+also provides trouble shooting hints.
+
+Please see [CHANGELOG.md](CHANGELOG.md) for a version history
+
+ [Beilstein Journal of Nanotechnology]: https://www.beilstein-journals.org/bjnano/
diff --git a/Master/texmf-dist/doc/latex/beilstein/beilstein-template.bib b/Master/texmf-dist/doc/latex/beilstein/beilstein-template.bib
new file mode 100644
index 00000000000..73edf0f2575
--- /dev/null
+++ b/Master/texmf-dist/doc/latex/beilstein/beilstein-template.bib
@@ -0,0 +1,319 @@
+@COMMENT{This BibTeX database consists of entries of all types of
+documents listed in the ``Instructions for Authors'', pp 5--6}
+@COMMENT{The references used in ``beilstein-template.tex'' are listed as well at the end of the file.}
+
+@COMMENT{Article within a journal}
+@ARTICLE{Constantino2001,
+author = {Constantino, M. G. and V. Lacerda, Jr. and Aragao, V.},
+year ={2001},
+journal = Molecules,
+volume = 6,
+pages = {770--776}
+}
+
+@COMMENT{Article within a journal with non-continuos (i.e.\ issue-based) pagination}
+@ARTICLE{Groeger2000,
+ author = {Gr\"{o}ger, H. and Sans, J. and G\"{u}thner, T.},
+ journal = {Chim. Oggi},
+ year = 2000,
+ volume = 18,
+ number = {3/4},
+ pages = {12--16}
+}
+
+@COMMENT{If no volume, but only a number is given, ``No.'' is added automatically}
+@ARTICLE{Wills1983,
+ author = {Wills, M. R. and Savory, J.},
+ journal = {Lancet},
+ year = 1983,
+ number = 2,
+ pages = {29}
+}
+
+@COMMENT{Article within a journal with article number}
+@COMMENT{The ``pages'' field is used for the article number.}
+@ARTICLE{Flamme2005,
+ author = {Flamme, E. M. and Roush, W. R.},
+ journal = {Beilstein J. Org. Chem.},
+ year = 2005,
+ volume = 1,
+ pages = {No. 7}
+}
+
+@COMMENT{Article within a journal supplement}
+@ARTICLE{Orengo1999,
+ author = {Orengo, C. A. and Bray, J. E. and Hubbard, T. and LoConte, L. and Sillitoe, I.},
+ journal = {Proteins},
+ year = {1999},
+ volume = 37,
+ number = {Suppl. S3},
+ pages = {149--170}
+}
+
+@COMMENT{Article within a journal with two separate editions or with translations/article within a journal with aditional Chemical Abstracts reference}
+@ARTICLE{Grubbs2006,
+ author = {Grubbs, R. H.},
+ journal = {Angew. Chem.},
+ year = 2006,
+ volume = 118,
+ pages = {3845--3850},
+ note = {{\emph{Angew. Chem., Int. Ed.} \textbf{2006,} \emph{45,} 3760--3765.}}
+}
+
+@COMMENT{In press article}
+@INPRESS{Schwartzman,
+ author = {Schwartzman, M. and S. J. Wind},
+ journal ={Nano Lett.}
+}
+
+@COMMENT{Patent}
+@COMMENT{``pages'' holds the patent number, ``journal'' the type of patent}
+@PATENT{Schimmel,
+ author = {Schimmel, T. and Xie, F. and Obermair, C.},
+ title = {Gate controlled atomic switch},
+ journal = {U.S. Pat. Appl.},
+ pages = {20090195300},
+ year = {Aug 6, 2009}
+}
+
+@COMMENT{Article within conference proceedings}
+@INPROCEEDINGS{Jones1996,
+author = {Jones, X.},
+title ={Zeolites and synthetic mechanisms},
+year = {1996},
+pages = {16--27},
+booktitle = {Proceedings of the First National Conference on Porous Sieves},
+publisher = {Butterworth-Heinemann},
+address = {Stoneham, MA},
+venue = {Baltimore, MD, June 27--30, 1996},
+editor = {Smith, Y.}
+}
+
+@COMMENT{Whole issue of a journal}
+@COMMENT{Instead of an author only an editor is given}
+@ARTICLE{OBrian2002,
+editor = {O'Brian, P.},
+title = {Recent developments in chiral lithium amide base chemistry},
+year ={2002},
+journal = {Tetrahedron},
+volume = 58,
+pages = {4567--4733}
+}
+
+@COMMENT{Whole conference proceedings}
+@Proceedings{Smith1996,
+editor = {Smith, Y.},
+title ={Proceedings of the First National Conference on Porous Sieves},
+year = {1996},
+address = {Stoneham, MA},
+venue = {Baltimore, MD, June 27--30, 1996},
+publisher = {Butterworth-Heinemann}
+}
+
+@COMMENT{Complete book}
+@BOOK{Rao2005,
+ author = {Rao, C. N. R. and Govindaraj, A.},
+ title = {Nanotubes and Nanowires},
+ publisher = {Royal Society of Chemistry},
+ address = {Cambridge, U.K.},
+ year = 2005
+}
+
+@COMMENT{Book edition}
+@BOOK{Borisenko2008,
+ author = {Borisenko, V. E. and Ossicini, S.},
+ title = {What is what in the Nanoworld},
+ edition = 2,
+ publisher = {Wiley-VCH},
+ address = {Berlin},
+ year = 2008
+}
+
+@COMMENT{Book chapter or article within book}
+@INCOLLECTION{Taylor2007,
+ author = {Taylor, R. and Burley, G. A.},
+ title = {Production, Isolation and Purification of Fullerenes},
+ booktitle = {Fullerenes -- Principles and Application},
+ editor = {Langa, F. and Nierengarten, J.-F.},
+ publisher = {Royal Society of Chemistry},
+ address = {Cambridge, U.K.},
+ year = 2007,
+ pages = {1--14}
+}
+
+@COMMENT{Book chapter or article within a multi-volume book}
+@INCOLLECTION{Farnum2003,
+ author = {Farnum, M. A. and DesJarlais, R. L. and Agrafiotis, D. K.},
+ title = {Molecular Diversity},
+ booktitle = {Handbook of Chemoinformatics: From Data to Knowledge},
+ editor = {Gasteiger, J.},
+ publisher = {Wiley-VCH},
+ address = {Weinheim, Germany},
+ year = {2003},
+ volume = {4},
+ pages = {1640--1686}
+}
+
+@COMMENT{Chapter of a book in a series}
+@INCOLLECTION{Goldfuss2003,
+ author = {Goldfuss, B.},
+ title = {Enantioselective addition of organolithiums to C=O groups},
+ booktitle = {Organolithiums in Enantioselective Synthesis},
+ editor = {Hodgson, D. M.},
+ series = {Topics in Organometallic Chemistry, Vol.~5},
+ publisher = {Springer},
+ address = {Berlin},
+ year = 2003,
+ pages = {21--35}
+}
+
+@COMMENT{Book with institutional author}
+@BOOK{AnnualReport,
+ author = {{Advisory Committee on Genetic Modification}},
+ title = {Annual Report},
+ year = 1999,
+ address = {London}
+}
+
+@COMMENT{Thesis}
+@PhDThesis{Pfrang2004,
+author = {Pfrang, A.},
+title ={Von den Fr\"uhstadien der Pyrokohlenstoffabscheidung bis zum Kompositwerkstoff -- Untersuchungen mit Rastersondenverfahren},
+year = {2004},
+school = {University of Karlsruhe, Germany}
+}
+
+@COMMENT{For online resources a new type ``WWW'' is introduced. The fields ``url'' and ``urldate'' hold the corresponding address and access date. Please note: the urldate is not formatted, so it has to be in the correct format already.}
+@WWW{Bozen2002,
+ title = {Proceedings of ``Molecular Informatics: Confronting Complexity'', May 13--16, 2002, Bozen, Italy},
+ url = {http://www.beilstein-institut.de/index.php?id=154},
+ urldate = {Sep 12, 2007}
+}
+
+@COMMENT{Software}
+@COMMENT{For software a field ``version'' can be used.}
+@SOFTWARE{Gaussian03,
+ title = {Gaussian 03},
+ version = {Revision C.02},
+ publisher = {Gaussian, Inc.},
+ address = {Wallingford, CT},
+ year = {2004}
+}
+
+@Comment{----------------------------------------------------------------------------------------------------------}
+@Comment{References used in ``beilstein-template.tex''.}
+
+@INCOLLECTION{Pornet2002,
+ author = {Pornet, J.},
+ title = {Product Subclass 32: Allenylsilanes},
+ booktitle = {Science of Synthesis},
+ editor = {Fleming, I.},
+ publisher = {Georg Thieme Verlag},
+ address = {Stuttgart},
+ year = {2002},
+ pages = {669--683},
+ volume = {4}
+}
+
+@ARTICLE{Masse1995,
+ author = {Masse, C. E. and Panek, J. S.},
+ journal = chreay,
+ year = 1995,
+ volume = 95,
+ pages = {1293--1316}
+}
+
+@ARTICLE{Jian1995,
+author = {Jian, J. and Smith, D. T. and Weinreb, S. M.},
+year ={1995},
+journal = joceah,
+volume = 60,
+pages = {5366--5367}
+}
+
+@ARTICLE{Weinreb1998,
+author = {Weinreb, S. M. and Smith, D. T. and Jian, J.},
+year ={1998},
+journal = syntbf,
+pages = {509--521}
+}
+
+@ARTICLE{Danheiser1980,
+author = {Danheiser, R. L. and Carini, D. J.},
+year ={1980},
+journal = joceah,
+volume = 45,
+pages = {3925--3927}
+}
+
+@ARTICLE{Danheiser1986,
+author = {Danheiser, R. L. and Carini, D. J. and Kwasigroch, C. A.},
+year ={1986},
+journal = joceah,
+volume = 51,
+pages = {3870--3878}
+}
+
+@ARTICLE{Danheiser1985,
+author = {Danheiser, R. L. and Kwasigroch, C. A. and Tsai, Y.-M.},
+year ={1985},
+journal = jacsat,
+volume = 107,
+ pages = {7233--7235}
+}
+
+@ARTICLE{Danheiser1985b,
+author = {Danheiser, R. L. and Fink, D. M.},
+year ={1985},
+journal = {Tetrahedron Lett.},
+volume = 26,
+ pages = {2513--2516}
+}
+
+@ARTICLE{Daidouji2005,
+author = {Daidouji, K. and Fuchibe, K. and Akiyama, T.},
+year ={2005},
+journal = orlef7,
+volume = 7,
+pages = {1051--1053}
+}
+@ARTICLE{Danheiser1981,
+author = {Danheiser, R. L. and Carini, D. J. and Basak, A.},
+year ={1981},
+journal = jacsat,
+volume = 103,
+pages = {1604--1606}
+}
+
+@ARTICLE{Danheiser1983,
+author = {Danheiser, R. L. and Carini, D. J. and Fink, D. M.},
+year ={1983},
+journal = tetrab,
+volume = 39,
+pages = {935--947}
+}
+
+@Article{Danheiser1987,
+author="R. L. Danheiser and D. A. Becker",
+journal="Heterocycles",
+year="1987",
+volume="25",
+pages="277-281",
+}
+
+@Article{Yadav2004,
+author="V. K. Yadav and V. Sriramurthy",
+journal="Org. Lett.",
+year="2004",
+volume="6",
+pages="4495-4498",
+note="Annulations leading to cyclohexenes are known, see reference 11",
+}
+
+@Article{Danheiser1987b,
+author="R. L. Danheiser and Y.-M. Tsai and D. M. Fink",
+journal="Org. Synth.",
+year="1987",
+volume="66",
+pages="1-4",
+}
diff --git a/Master/texmf-dist/doc/latex/beilstein/beilstein-template.tex b/Master/texmf-dist/doc/latex/beilstein/beilstein-template.tex
new file mode 100644
index 00000000000..82a67006925
--- /dev/null
+++ b/Master/texmf-dist/doc/latex/beilstein/beilstein-template.tex
@@ -0,0 +1,238 @@
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+%% This is a (brief) example using the beilstein class.
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+%% If issues arise when submitting your manuscript, you may want to
+%% un-comment the next line. This provides information on the
+%% version of every file you have used. That way the maintainer of
+%% the class can handle the issue much easier.
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+%%\listfiles
+
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+%% The document class does not have many options yet. It accepts an
+%% optional keyval option for the manuscript type and options for the
+%% language and inputencoding used.
+%% These are for the manuscript type:
+%% manuscript=fullresearchpaper (default),
+%% manuscript=letter,
+%% manuscript=commentary,
+%% manuscript=review,
+%% manuscript=bookreport.
+%%
+%% For the language (in terms of hyphenation):
+%% american -> American English (default),
+%% british, english -> British English.
+%%
+%% For the input encoding:
+%% latin1 (default),
+%% utf8,
+%% applemac.
+%%
+%% The defaults are [manuscript=fullresearchpaper,american,latin1].
+%% Please not, that you should consider using the utf8 option as this
+%% is the standard encoding nowadays.
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+\documentclass[utf8]{beilstein}
+
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+%% Place any additional packages needed here. Only include packages
+%% which are essential to avoid problems later. The class already
+%% loads some useful packages, so please have a look at the
+%% documentation.
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+\usepackage{xspace}
+
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+%% Place any additional macros here. Please use \newcommand* where
+%% possible, and avoid layout-changing macros (which are not used
+%% when typesetting).
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+\newcommand*{\CHCL}{\chem{CH_2Cl_2}}
+\newcommand*{\HNMR}{\chem{^{1}H~NMR}\xspace}
+\newcommand*{\CNMR}{\chem{^{13}C~NMR}\xspace}
+
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+%% Beginning of the article
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+\begin{document}
+
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+%% Meta-data block
+%% ---------------
+%% The title of the article is given with the usual \title command.
+%%
+%% Each author should be given as a separate \author command.
+%%
+%% For corresponding authors please use \author* and give the email
+%% address as a second mandatory argument.
+%%
+%% The affiliation of authors is given after the authors; the
+%% affiliations are numbered consecutively.
+%%
+%% If some authors have the same affiliation you can use the optional
+%% argument of \author and \author* to give the number of that
+%% affiliation.
+%%
+%% The whole block is printed with the \maketitle command at the very
+%% end.
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+\title{Synthesis of highly substituted allenylsilanes by alkylidenation of silylketenes}
+\author*{Stephen P. Marsden}{s.p.marsden@leeds.ac.uk}
+\affiliation{School of Chemistry, University of Leeds, Leeds LS2 9JT, United Kingdom}
+\author{Pascal C. Ducept}
+\affiliation{Department of Chemistry, Imperial College London, London SW7 2AY, United Kingdom}
+\maketitle
+
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+%% The document should begin with an abstract, if appropriate. If one
+%% is given and should not be, a warning is issued.
+%%
+%% For the three parts of the abstract, ``Background'', ``Results''
+%% and ``Conclusions'', the corresponding commands should be used.
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+\begin{abstract}
+\background Allenylsilanes are useful intermediates in organic synthesis. An attractive,
+convergent but little used approach for their synthesis is the alkylidenation of stable silylketenes. Reactions thus far have been limited to the use of unsubstituted silylketenes (or equivalents) with stabilised or semi-stabilised ylides only. The current study explores the reactions of substituted ketenes prepared through rhodium(II)-mediated rearrangement of silylated diazoketones.
+\results A range of novel 1,3-disubstituted and 1,3,3-trisubstituted allenylsilanes were prepared using stabilised and semi-stabilised ylides. Alkylidenation with non-stabilised phosphorus ylides was not viable, but the use of titanium-based methylenating reagents was successful, allowing access to 1-substituted allenylsilanes.
+\conclusion Many novel allenylsilanes may be accessed by alkylidenation of substituted silylketenes. Importantly, for the first time, simple methylenation of silylketenes has been achieved using titanium carbenoid-based reagents.
+\end{abstract}
+
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+%% Keywords can be given with the \keywords command which takes five
+%% arguments. The arguments have to be sorted.
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+\keywords{allenylsilanes; rhodium(II) octanoate-mediated rearrangement; silylketenes; titanium carbenoids; ylide}
+
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+%% The main text starts right here. For each required and optional
+%% section of the chosen document type a special command is defined.
+%%
+%% It is strongly recommended to use BibTeX for managing references.
+%% Citations and citation lists can be given with the \cite command.
+%% Please note, that not all references have been added to the
+%% example document.
+%%
+%% For references in floats \cite is locally redefined to
+%% adds the reference to the end of the list of references.
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+\section{Introduction}
+Allenylsilanes are versatile intermediates for organic synthesis \cite{Pornet2002,Masse1995}. They have two main modes of reactivity: firstly, as propargyl anion equivalents in thermal \cite{Jian1995,Weinreb1998} or Lewis acid-mediated \cite{Danheiser1980,Danheiser1986} addition to carbonyls, acetals and imines, and secondly as three-carbon partners in [3+2] annulation reactions. Thus, reaction with aldehydes \cite{Danheiser1985}, imines/iminiums \cite{Danheiser1985,Daidouji2005}, enones \cite{Danheiser1981,Danheiser1983,Danheiser1985b} and nitrosyl cations \cite{Danheiser1987} leads to dihydrofurans, dihydropyrroles, cyclopentenes and isoxazoles respectively \cite{Yadav2004}. In most cases the silicon is retained in the final product and can be used as a handle for further synthetic elaboration.
+
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+%% When referencing objects, LaTeX offers a label--ref mechanism.
+%% The beilstein class extends this approach with the \cref command,
+%% that adds the corresponding type of the object as well.
+%%
+%% Tables, figures and schemes must have a single column or double
+%% column width. To make life easier, some commands are defined.
+%%
+%% Captions (legends) will always be added at the correct place no
+%% matter where you put in the source code.
+%% Please note: labels always have to come /after/ the \caption.
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+Amongst the myriad methods to prepare allenylsilanes \cite{Pornet2002,Danheiser1987b}, an attractive disconnection is to consider a Wittig-type alkylidenation of a silylketene (\cref{fig:AlkylidenationApproach}).
+\begin{figure}
+\caption{Alkylidenation approach to the synthesis of allenylsilanes.}
+\label{fig:AlkylidenationApproach}
+\includegraphics[width=8.2cm,keepaspectratio]{figure1}
+%% \sglcolfigure{figure1}
+\end{figure}
+
+[\ldots]
+
+\section{Results and Discussion}
+Our investigations began with the preparation of substituted silylketenes \CN{1} as substrates for the alkylidenation chemistry. This was carried out under our previously reported conditions for rhodium(II) octanoate-mediated rearrangement of silyl diazoketones \CN{2}, which in turn were prepared by \textit{C}-silylation of the parent diazoketones \CN{3} with triethylsilyl triflate (\cref{scheme:1}). It should be noted that while the alkyl-substituted silylketenes are relatively stable and show little decomposition at room temperature over several days, the (hetero)aromatic-substituted silylketenes are much less robust and should be used quickly or stored in a freezer.
+
+\begin{scheme}
+\caption{Synthesis of substituted silylketenes \CN{1}.}
+\label{scheme:1}
+\includegraphics[width=8.2cm,keepaspectratio]{scheme1}
+\end{scheme}
+
+[\ldots]
+
+With the requisite silylketenes in hand, attention turned to their reaction with the carboethoxy-stabilised phosphoranes \CN{4} and \CN{5}. At the outset, it was by no means certain that these would react efficiently with substituted silylketenes \CN{1} since it is well documented that nucleophiles attack silylketenes \textit{anti} to the silicon, i.e.\ the phosphoranes would be approaching from the same side as the \chem{R^1}-substituent. Since in all previous examples this substituent has been a hydrogen atom, the extension to bulkier substituents could not be taken for granted. In the event, however, we were pleased to find that in nearly all cases the desired allenylsilanes were formed in moderate to excellent yield (\cref{scheme:2}, \cref{tab:1}, see \cref{si:1} for full experimental data).
+\begin{scheme}
+\includegraphics[width=8.2cm,keepaspectratio]{scheme2}
+\caption{Reaction of substituted silylketenes with ester-stabilised phosphoranes.}
+\label{scheme:2}
+\end{scheme}
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+%% Tables are a bit special. Only there the \footnote is allowed for
+%% Beilstein publications.
+%%
+%% As for figures and schemes sglcoltabular and dblcoltabular can be
+%% used to get tables of the correct width. If you do not want to
+%% messure the columns you can use parameter ``X'' of the tabularx
+%% package for one column or more to get equal-sized columns.
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+
+\begin{table}
+\caption{Reaction of substituted silylketenes with ester-stabilised phosphoranes.}
+\label{tab:1}
+\begin{dblcoltabularx}{|l|l|l|l|l|X|X|}\hline
+\bfseries Entry & \bfseries Ketene & \bfseries Ylide & \bfseries Temp [\celsius] & \bfseries \textit{t} [h] & \bfseries Solvent & \bfseries Yield 6/7 (8)\\\hline
+1 & \CN{1a} & \CN{4} & 80 & 24 & PhH & 54\,\%\\\hline
+2 & \CN{1a} & \CN{5} & rt & 3 & \CHCL & 60\,\%\\\hline
+3 & \CN{1b} & \CN{4} & 110 & 24 & toluene & 45\,\%\\\hline
+4 & \CN{1b} & \CN{5} & reflux & 24 & \CHCL & 77\,\%\\\hline
+5 & \CN{1c} & \CN{4} & 80 & 24 & PhH & 60\,\%\\\hline
+6 & \CN{1c} & \CN{5} & rt & 6 & \CHCL & 81\,\%\\\hline
+7 & \CN{1d} & \CN{4} & 110 & 48 & toluene & 22\,\%%
+ \footnote{60\,\% of starting material recovered}\\\hline
+8 & \CN{1d} & \CN{5} & 80 & 48 & toluene & 78\,\%\\\hline
+9 & \CN{1e} & \CN{4} & 80 & 24 & PhH & 55\,\% (7\,\%)\\\hline
+10 & \CN{1f} & \CN{4} & 60 & 5 & \CHCL & 44\,\% (3\,\%)\\\hline
+11 & \CN{1h} & \CN{4} & rt & 6 & \CHCL & 0\,\% (57\,\%)\\\hline
+12 & \CN{1h} & \CN{4} & 50 & 1 & \CHCL & 7\,\% (23\,\%)\\\hline
+13 & \CN{1i} & \CN{4} & rt & 10 & \CHCL & 0\,\% (67\,\%)\\\hline
+14 & \CN{1i} & \CN{5} & rt & 2 & \CHCL & 98\,\%\\\hline
+15 & \CN{1j} & \CN{4} & 80 & 12 & PhH & 74\,\% (19\,\%)\\\hline
+\end{dblcoltabularx}
+\end{table}
+
+As expected, reactions with the more substituted ylide \CN{4} were significantly slower than those with the parent ylide \CN{5} (compare reaction temperatures and times, entries 1, 3 and 5 versus entries 2, 4 and 6). [...]
+
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+%% The Supporting Information is an essential part of many articles.
+%% They are given inside the ``suppinfo'' environment with the
+%% \sifile command which gets the following mandatory arguments:
+%% #1: File name
+%% #2: File type
+%% #3: Descriptive File title
+%% A long description can be given using the optional argument.
+%%
+%% You can label each entry and reference it in the text.
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+\begin{suppinfo}
+Supporting information features copies of \HNMR spectra of silylated diazoketones \CN{2} and silylketenes \CN{1}, plus \chem{{}^1H} and \CNMR spectra of allenylsilanes \CN{6}, \CN{7}, and \CN{14}--\CN{19}.
+\sifile{S1.pdf}{PDF}{Experimental part}\label{si:1}
+\sifile{S2.pdf}{PDF}{NMR spectra of compounds \CN{1}, \CN{2}, \CN{6} and \CN{7}}
+\sifile{S3.pdf}{PDF}{NMR spectra of compounds \CN{14--19}}
+\end{suppinfo}
+
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+%% The "Acknowledgements" section can be given in all manuscripts.
+%% This should be done within the ``acknowledgements'' environment,
+%% which will make the correct section title.
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+\begin{acknowledgements}
+We acknowledge EPSRC grant GR/L60135/01 (PCD) and generous unrestricted research funding from Pfizer for financial support.
+\end{acknowledgements}
+
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+%% The appropriate \bibliography command should be placed here.
+%% Notice that the class file automatically sets \bibliographystyle
+%% and also names the section correctly.
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+\bibliography{beilstein-template}
+\vspace{3cm}
+This article is published in full length in \textit{Beilstein J. Org. Chem.}
+\textbf{2005}, \textit{1}, No. 5.
+
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+%% That's it. Ending the document finishes the article. Happy TeXing!
+%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
+\end{document}
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