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\documentclass{article}
\usepackage[T1]{fontenc}
\usepackage{graphicx,chemscheme}
\usepackage[inactive,final]{pst-pdf}
\begin{document}
\floatcontentscentre
An example file for PDFLaTeX use.
\begin{scheme}
\schemeref{IMesHCl}
\schemeref{IMes}
\includegraphics{scheme-two}
\caption{A scheme with automated compound numbers.}
\label{sc:scheme-one}
\end{scheme}
\end{document}
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