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+\documentclass{report}
+\usepackage{german,rotating,times}
+\usepackage[latin1]{inputenc}
+\begin{document}
+
+\begin{table}
+\caption{Anwendungsübersicht über verschiedene
+Derivatisierungsreagenzien I}
+\begin{tabular}{l*6{c}}
+\rule{0mm}{27mm} % Freihalten in Höhe der Legende
+\hfil\begin{rotate}{60}Reagenz\end{rotate}\hfil &
+\begin{rotate}{60}Alkohole\end{rotate} &
+\begin{rotate}{60}Amine\end{rotate} &
+\begin{rotate}{60}Aminosäuren\end{rotate} &
+\begin{rotate}{60}Carbonsäuren\end{rotate} &
+\begin{rotate}{60}Hydroxylgruppen\end{rotate} &
+\begin{rotate}{60}Phenole\end{rotate} \\
+\hline
+Bortrifluorid-Methanol-Komplex & & & x & & & \\
+Chlortrimethylsilan & x & x & x & x & x & x \\
+Dichlordimethylsilan & & & x & & &\\
+Hexamethyldisiloxan & & & & & x & \\
+N-Methyl-bis(trifluoracetamid) & x & x & & & & x \\
+\hline
+\end{tabular}
+\end{table}
+\end{document}